MétaCan
Menu
Back to cohort
Record W2338771374 · doi:10.1177/0892705716632856

Synthesis and characterization of lignin–melamine–formaldehyde resin

2016· article· en· W2338771374 on OpenAlex
Amadou Diop, Kokou Adjallé, Benjamin Boëns, Daniel Montplaisir, Simon Barnabé

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of Thermoplastic Composite Materials · 2016
Typearticle
Languageen
FieldEngineering
TopicLignin and Wood Chemistry
Canadian institutionsUniversité du Québec à Trois-Rivières
Fundersnot available
KeywordsFourier transform infrared spectroscopyDifferential scanning calorimetryFormaldehydeLigninMelamineMelamine resinThermogravimetric analysisPolymer chemistryMaterials scienceCuring (chemistry)Yield (engineering)Amine gas treatingNuclear chemistryChemistryOrganic chemistryChemical engineeringComposite material

Abstract

fetched live from OpenAlex

Lignin–melamine–formaldehyde (LMF) resin was prepared by three steps: (i) tosylation of lignin, (ii) synthesis of lignin-melamine (LM) copolymer, and (iii) formation of methylol LM. The synthesized resins were characterized by Fourier transform infrared (FTIR) spectroscopy and phosphorous 31 nuclear magnetic resonance analysis. The curing parameters of LMF resin were determined by differential scanning calorimetry (DSC) and thermal gravimetric analysis. The yield of tosylation is 80%. The FTIR spectrum of tosylated lignin shows the presence of two new bands at 1171 and 1370 cm −1 . The formation of the LM was demonstrated by the disappearance of both bands and appearance of the absorbances at 3115, 3312, 3415, and 3470 cm −1 corresponding to the stretching vibrations of primary and secondary amine. The peaks observed at 147.0 and 148.5 ppm are attributed to the new aliphatic hydroxyl groups formed by the methylolation of LM. One exothermic peak was observed in the DSC analysis indicating a one cross-linking reaction.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.301

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.173
Teacher spread0.169 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it