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Record W2339501191 · doi:10.1002/cjce.22512

Investigations on the degradation of an antibiotic Cephalexin using suspended and supported TiO<sub>2</sub>: Mineralization and durability studies

2016· article· en· W2339501191 on OpenAlexvenueno aff
Palak Bansal, Anoop Verma, Kashish Aggarwal, Amanjit Singh, Saurabh Gupta

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2016
Typearticle
Languageen
FieldEnvironmental Science
TopicPharmaceutical and Antibiotic Environmental Impacts
Canadian institutionsnot available
Fundersnot available
KeywordsMineralization (soil science)PhotocatalysisDegradation (telecommunications)DurabilityNuclear chemistrySlurryMaterials scienceNitrateNitriteWastewaterInorganic ionsCatalysisChemistryEnvironmental engineeringIonComposite materialEnvironmental scienceOrganic chemistryNitrogen

Abstract

fetched live from OpenAlex

Rising levels of antibiotics in treated wastewater pose a great threat to human health worldwide. The present study shows degradation studies of antibiotic Cephalexin using slurry and innovative fixed‐bed photocatalysis under UVA (365 nm) irradiations. A UV‐spectrophotometer/HPLC was used for analyzing the decay of Cephalexin. Studies showed that variation in UV intensity, dose variation of TiO2and H2O2,area by volume (A/V), and pH affect the degradation to a great extent. The degradation rate followed pseudo‐first order kinetics with optimized conditions for degrading the antibiotic being TiO21.0 g · L−1, H2O20.15 mL, with UV intensity of 25 W · m−2. The COD decrease (80 %) with the generation of nitrite, nitrate, and sulphate ions confirmed the mineralization of the selected compound. TiO2‐coated spherical cement beads were used for fixed‐bed studies, which eliminates the implications of slurry mode photocatalysis. The beads were recycled for at least 50 cycles, which confirmed the durability of the catalyst, and characterized by SEM‐EDAX. Attempts were made to study the pilot‐scale fixed‐bed baffled solar reactor for degrading Cephalexin, which confirmed 70 % degradation after 10 h.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.040
GPT teacher head0.251
Teacher spread0.211 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations37
Published2016
Admission routes1
Has abstractyes

Explore more

Same venueThe Canadian Journal of Chemical EngineeringSame topicPharmaceutical and Antibiotic Environmental ImpactsFrench-language works237,207