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Record W2344519499

Evaluation of a Spectrophotometric Method for Practical and Cost Effective Quantification of Fulvic Acid

2007· article· en· W2344519499 on OpenAlexaff
Daqing Gan, Shaban Kotob, D.S. Walia

Bibliographic record

Venuenot available
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicMarine and coastal ecosystems
Canadian institutionsOptech (Canada)
Fundersnot available
KeywordsFulvic acidHumic acidChemistryGravimetric analysisCalibration curveCalibrationAbsorption (acoustics)PrecipitationEnvironmental chemistryChromatographyOrganic chemistryDetection limitMathematicsMaterials science
DOInot available

Abstract

fetched live from OpenAlex

A large number of organic humic products are increasingly being applied worldwide especially in agricultural applications. Humic substances can be fractionated into three components: humic acid, fulvic acid and insoluble humin. A standard method based on acid precipitation is gaining acceptance for quantification of humic acid as the humic acid precipitates at pH < 2 and thus can be quantified by gravimetric measurements. However, the fulvic acid component remains in solution at all pH conditions and there is no practical and cost effective method available for measuring fulvic acid. This paper presents the results of our evaluation of spectrophotometric analysis of the fulvic acid content of commercial humic products. Based on the assumption that the optical properties of fulvic acids are independent of their sources, a calibration curve showing a linear relationship between varying concentrations of an IHSS standard fulvic acid and their UV/vis absorption at multiple wavelengths was established. The concentrations of fulvic acid in a variety of commercial products were then obtained by measuring the samples UV/vis absorption and applying the established calibration curve. The calculated fulvic acid concentrations were in reasonable agreement with the values obtained from carbon analysis of the test samples after corrections. Permanent URL: http://hdl.handle.net/2047/d10006060

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.006
metaresearch head score (Gemma)0.005
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.006
Threshold uncertainty score0.034

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0060.005
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0030.002
Science and technology studies0.0010.001
Scholarly communication0.0010.001
Open science0.0020.001
Research integrity0.0030.001
Insufficient payload (model declined to judge)0.0020.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.051
GPT teacher head0.357
Teacher spread0.306 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations20
Published2007
Admission routes1
Has abstractyes

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