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Record W2346656190 · doi:10.1002/cjce.22528

Capacity assessment and potential for reuse of calcined Bofe bentonitic clay for adsorption of nickel

2016· article· en· W2346656190 on OpenAlexvenueno aff
Melissa Gurgel Adeodato Vieira, Ambrósio Florêncio de Almeida Neto, Marcelino Luís Gimenes, Meuris Gurgel Carlos da Silva

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2016
Typearticle
Languageen
FieldMaterials Science
TopicClay minerals and soil interactions
Canadian institutionsnot available
FundersConselho Nacional de Desenvolvimento Científico e TecnológicoCoordenação de Aperfeiçoamento de Pessoal de Nível SuperiorFundação de Amparo à Pesquisa do Estado de São Paulo
KeywordsCalcinationAdsorptionNickelReuseMaterials scienceEnvironmental scienceChemistryWaste managementMetallurgyEngineeringPhysical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract This work aims to evaluate different eluents in cycles of nickel adsorption/desorption on calcined Bofe clay. The following eluents were used sequentially for nickel desorption: H 2 SO 4 0.25 mol/L, NaCl 1.0 mol/L, CaCl 2 0.10 mol/L, and EDTA 0.10 mol/L. Physical‐chemical characterization analyses of Bofe clay samples were carried out under different conditions to evaluate the effect of the remaining metal on the adsorbent submitted to adsorption/desorption cycles. The adsorbent material was characterized by the following techniques: energy dispersive X‐ray spectroscopy (EDX), thermogravimetry (TG), differential scanning calorimetry (DSC), X‐ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and N 2 physisorption (BET). Statistica 5.0 was used as a computational tool to adjust the rate quasi‐chemical solution to the experimental data of the breakthrough curves. From the new function obtained, breakthrough curves for different bed heights could be also simulated. An increase of the clay surface area and a reduction of real density after the passage of the four eluents were observed. Among the tested eluents, NaCl (1 mol/L) presented the highest percentage of desorption (88.08 %). The nickel adsorption/desorption cycles study showed that Bofe clay retains the same nickel adsorption capacity throughout the four evaluated cycles.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.150

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.260
Teacher spread0.239 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2016
Admission routes1
Has abstractyes

Explore more

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