Electrochemical behaviors and determination of baicalin at a glassy carbon electrode
Bibliographic record
Abstract
Electrochemical behaviors of Baicalin have been examined by means of linear-sweep voltammetry, cyclic voltammetry and normal pulse voltammetry, and a differential pulse voltammetry for determination of Baicalin in urine and serum samples has been established. The (adsorption) behavior of Baicalin at the glassy carbon electrode was investigated. The adsorption corresponded to a Frumkin type isotherm and the free energy of adsorption was calculated to be -35.01 kJ/mol at 22 ℃. Bulk electrolytic method was used to measure the number of electrons transferred in the oxidation reaction, and the mechanism of the electrode reaction was suggested. The detection limit is 2.80×10~(-10) mol/L, and the relative standard deviation(RSD) is 2.02% for 5.60×10~(-7) mol/L Baicalin (n=6).
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.002 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".