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Record W2383645651

Characterization of Residue (C5-C7) Asphaltene (Soluble in n-Heptane but Insoluble in n-Pentane)

2011· article· en· W2383645651 on OpenAlexaboutno aff
Suoqi Zhao

Bibliographic record

VenueJournal of Petrochemical Universities · 2011
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsnot available
Fundersnot available
KeywordsAsphaltenePentaneHeptaneChemistryAromaticityAlkaneResidue (chemistry)StackingOrganic chemistryHydrocarbonMolecule
DOInot available

Abstract

fetched live from OpenAlex

(C5-C7) asphaltene(soluble in n-heptane but insoluble in n-pentane) of Canada oilsand bitumen vacuum residue(VTB) was charactered and compared with n-pentane asphaltene and n-heptane asphaltene with the help of GPC,XRD,1H-NMR,SEM measurements and HyperChem simulation.(C5-C7) asphaltene has a small yield of 9.80% and composes mainly small moleculars,whose average structure unit possesses the lowest aromaticity and aromatic ring number but maximum naphthenic ring number(2.60).The length of(C5-C7) asphaltene alkane chains connected with aromatic rings is 0.5 more carbons than the other two asphaltenes.There is no aromatic sheet stacking structures existing in(C5-C7) asphaltene,which is different from n-pentane and n-heptane asphaltenes.(C5-C7) asphaltene has the biggest stable energy(266.73 kJ/mol),leading to a worst stability,whose particles have a large dimension and smooth surface.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.012
Threshold uncertainty score0.706

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.210
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2011
Admission routes1
Has abstractyes

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