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Record W2385061439

Study on the inclusion between diacerein and cyclodextrin by spectrophotometry

2013· article· en· W2385061439 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueApplied Chemical Industry · 2013
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicLipid Membrane Structure and Behavior
Canadian institutionsScience North
Fundersnot available
KeywordsChemistryCyclodextrinEndothermic processExothermic reactionHydrogen bondvan der Waals forceSpectrophotometryInclusion compoundNuclear chemistryAdsorptionChromatographyPhysical chemistryOrganic chemistryMolecule
DOInot available

Abstract

fetched live from OpenAlex

The inclusions between diacerein and beta-cyclodextrin(β-CD) and hydroxypropyl-beta-cyclocextrin(HP-β-CD) were investigated by spectrophotometry at the physiological conditions.A spontaneous exothermic process was produced in the reaction of diacerein and β-CD according to thermodynamic parameters such as ΔrHm 0 and ΔrGm 0.Furthermore,it was concluded that diacerein interacted mainly with β-CD by hydrogen bond and Van Der Waals force according to thermodynamic parameters such as ΔrHm 0 and ΔrSm 0.At the same time,it was concluded that a spontaneous endothermic process was produced in the reaction of diacerein with HP-β-CD according to thermodynamic parameters such as ΔrHm 0 and ΔrGm 0.In addition,it was a hydrophobic interaction process by entropy driving according to thermodynamic parameters such as ΔrHm 0 and ΔrSm 0 in the reaction of diacerein and HP-β-CD.The results were in agreement with the experimental ones.The ratios of inclusion were all 1 ∶ 1 in diacerein with β-CD and HP-β-CD.And the bonding constant in diacerein-HP-β-CD system was more than the one in dicerein-β-CD system at the same temperature.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score0.517

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.001
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.252
Teacher spread0.240 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it