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Record W2397212000 · doi:10.1002/app.43771

Sustainable biobased blends from the reactive extrusion of polylactide and acrylonitrile butadiene styrene

2016· article· en· W2397212000 on OpenAlex
Ryan Vadori, Manjusri Misra, Amar K. Mohanty

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of Applied Polymer Science · 2016
Typearticle
Languageen
FieldMaterials Science
Topicbiodegradable polymer synthesis and properties
Canadian institutionsUniversity of Guelph
Fundersnot available
KeywordsMaterials scienceExtenderCopolymerIzod impact strength testExtrusionFourier transform infrared spectroscopyAcrylonitrile butadiene styreneReactive extrusionAcrylonitrileMolding (decorative)Composite materialPolymer chemistryPolymerChemical engineeringUltimate tensile strengthPolyurethane

Abstract

fetched live from OpenAlex

ABSTRACT Polymer blends containing poly(lactic acid) (PLA) and acrylonitrile butadiene styrene (ABS) with high biobased content (50%) were made by extrusion and injection molding. Two additives, one acrylic copolymer and one chain extender were used separately and in combination to increase mechanical properties. Interestingly, the combination of both the acrylic copolymer and chain extender worked to synergistically increase the impact strength by almost 600%. This was attributed to the complementary additive toughening effects which allowed increased energy dissipation of the blend at high speed testing, such as in the impact test. Morphology and rheology investigation showed that the two additives worked together to vastly change the dispersion and phase sizes, suggesting a decreased tension between the PLA and ABS. Finally, Fourier transform infrared spectroscopy supported the evidence that the epoxy groups of the chain extender undergo ring opening to react with the functional groups of the PLA. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133 , 43771.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.047
Threshold uncertainty score0.500

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.214
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it