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Record W24593016 · doi:10.2166/wqrj.2001.038

Acid Hydrolysis Lignin as a Sorbent for Naphthalene

2001· article· en· W24593016 on OpenAlexafffund
Angela Keane, Subhasis Ghoshal

Bibliographic record

VenueWater Quality Research Journal · 2001
Typearticle
Languageen
FieldEnvironmental Science
TopicAdsorption and biosorption for pollutant removal
Canadian institutionsMcGill University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsSorptionLigninChemistryFreundlich equationHydrolysisNaphthaleneOrganic chemistryAdsorptionChromatography

Abstract

fetched live from OpenAlex

Abstract Lignin, a major polymeric constituent of woody plant tissue, is an abundant source of natural organic matter available as a waste product from the pulp and paper and the fuel ethanol industries. In this study, the sorptive capacity of acid hydrolysis lignin for naphthalene, a representative nonpolar hydrophobic organic compound (HOC), was investigated. When powdered lignin is mixed with distilled water, dissolved and/or colloidal organic matter leaches into the aqueous phase imparting a cloudy yellowish colour. A washing and filtering protocol was developed for pretreating the lignin employed in the sorption studies. Results from batch sorption experiments showed that acid hydrolysis lignin has a strong affinity for naphthalene. The Freundlich isotherm coefficients obtained indicate that the sorption isotherm for naphthalene on hydrolysis lignin is nearly linear. A modified Freundlich equation was employed in order to compare sorption data for HOCs on lignin and activated carbon through the use of unit equivalent coefficients. The results presented in this research and in the literature suggest that the two sorbents are comparable in terms of sorption coefficients. It was determined that acid hydrolysis lignin is unsuitable for use in a packed bed since pumping a naphthalene solution through a column packed with lignin caused the wet lignin to become significantly hardened over time, resulting in a large pressure drop across the system.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.006
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.533
Threshold uncertainty score0.996

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0060.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0130.004

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.120
GPT teacher head0.412
Teacher spread0.291 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2001
Admission routes2
Has abstractyes

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