Aluminum environments in synthetic Ca-Tschermak clinopyroxene (CaAlAlSiO <sub>6</sub> ) from Rietveld refinement, <sup>27</sup> Al NMR, and first-principles calculations
Bibliographic record
Abstract
27Al magic-angle spinning nuclear magnetic resonance (MAS NMR) and 27Al triple quantum (3Q) MAS NMR spectroscopy have been performed at 21.1 Tesla (T), as a direct probe of environment around Al in synthetic Ca-Tschermak's clinopyroxene, CaAlAlSiO6, henceforward referred to as CaTs. For comparison, 27Al MAS NMR of CaTs has also been performed at 14.1 T. The 27Al 3QMAS NMR spectrum of CaTs has revealed various local environments around octahedral and tetrahedral Al, both ordered and disordered, symmetrical, and distorted. Rietveld refinement of powder X‑ray diffraction data has confirmed the high-temperature, long-range disordered C2/c structure for this sample.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".