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Record W2485287754 · doi:10.1002/adfm.201602103

Efficient Lightweight Supercapacitor with Compression Stability

2016· article· en· W2485287754 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueAdvanced Functional Materials · 2016
Typearticle
Languageen
FieldMaterials Science
TopicSupercapacitor Materials and Fabrication
Canadian institutionsMcMaster University
FundersNatural Sciences and Engineering Research Council of CanadaMcMaster University
KeywordsMaterials scienceSupercapacitorCurrent collectorCapacitanceFabricationElectrodeComposite materialCyclic voltammetryNanotechnologyElectrochemistryElectrolyte

Abstract

fetched live from OpenAlex

This paper reports the fabrication of an electrochemical supercapacitor (ES) with high gravimetric and areal capacitances, achieved at a high mass ratio of active material to current collector. The active material, polypyrrole, is in situ polymerized in an aerogel‐based current collector composed of crosslinked cellulose nanocrystals (CNCs) and multiwalled carbon nanotubes (MWCNTs). Mechanical robustness, flexibility, and low impedance of the current collectors are achieved by the chemical crosslinking of CNC aerogels and efficient dispersion of MWCNTs through the use of bile acid as a dispersant. Furthermore, the advanced electrode design results in low contact resistance. A single‐electrode areal capacitance of 2.1 F cm −2 is obtained at an active mass loading of 17.8 mg cm −2 and an active material to current collector mass ratio of 0.57. Large area ES electrodes and devices show flexibility, excellent compression stability at 80% compression, and electrochemical cyclic stability over 5000 cycles. Moreover, good retention of capacitive properties is achieved at high charge–discharge rates and during compression cycling. The results of this investigation pave the way for the fabrication of advanced lightweight ES, which can be used for energy storage in wearable electronic devices and other applications.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.015
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0160.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.216
Teacher spread0.199 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it