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Record W2486881266 · doi:10.1177/026248930302200502

Evaluation of HFC-245fa as an Alternative Blowing Agent for Extruded Polystyrene

2003· article· en· W2486881266 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueCellular Polymers · 2003
Typearticle
Languageen
FieldMaterials Science
TopicPolymer Foaming and Composites
Canadian institutionsNational Research Council Canada
Fundersnot available
KeywordsBlowing agentMaterials sciencePolystyrenePolyurethaneComposite materialPropaneExtrusionChemical engineeringPolymerOrganic chemistryChemistry

Abstract

fetched live from OpenAlex

The need for replacing conventional CFCs with alternative blowing agents has led to the development of many candidates. Among those, HFC-245fa is targeted as one of the most promising for the replacement of HCFC-141b in polyurethane foams. However, the low thermal conductivity of HFC-245fa and its interesting near room-temperature boiling point may render it suitable for other applications such as polystyrene insulating foam board manufacturing. This work investigates the use of HFC-245fa as a potential physical blowing agent for extruded thermoplastic foams. The process was monitored using ultrasonic probes, which reveals information on the solubility behavior of the gas in the molten state. Results showed that at 190°C, HFC-245fa could be incorporated in molten polystyrene up to about 7 wt.% and generate homogeneous solutions. Higher concentrations revealed evidence of heterogeneous conditions as seen in the attenuation signal. Three concentrations of blowing agent (5, 6 and 7 wt.%) were used to produce foam samples at lower extrusion temperatures. Increasing the concentration of blowing agent or nucleating agent greatly affected the expansion profile of the foam samples. Thus, lower densities could be achieved by using an optimal combination of both.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.010
Threshold uncertainty score0.804

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.039
GPT teacher head0.298
Teacher spread0.258 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it