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Record W2488243626 · doi:10.14288/1.0050348

An examination of trace metal contamination and land use in an urban watershed

2009· article· en· W2488243626 on OpenAlexaboutno aff
Donald W. McCallum

Bibliographic record

VenuecIRcle (University of British Columbia) · 2009
Typearticle
Languageen
FieldEnvironmental Science
TopicWater Quality and Pollution Assessment
Canadian institutionsnot available
Fundersnot available
KeywordsContaminationWatershedEnvironmental scienceTRACE (psycholinguistics)Trace metalEnvironmental chemistryChemistryMetalComputer scienceEcologyBiology

Abstract

fetched live from OpenAlex

The Brunette River Watershed is intensely urbanized, occupying 7200 hectares in the geographic centre of the Greater Vancouver Regional District in British Columbia. This study examines lake, stream, and street sediment trace metal contaminant history in the watershed in relation to changing land uses. Contamination of Burnaby Lake surface sediments with Pb, Cu, Zn, and Cd is indicated by their respective enrichment factors of 10, 6, 3.8, and 1.5. Chromium, Ni, Mg, Fe, and Mh are not enriched in the surface sediments. Calculated fluxes of Pb, Cu, and Zn entering Burnaby Lake are from 3 to 10 times higher than measured in two comparable urban lakes. Stream contamination is indicated by the failure of all 33 stream stations to meet watershed sediment criteria for Pb, Cu, and Zn and 13 stream stations for Hg. Trace metal concentrations in Burnaby Lake sediments increased steadily from 1950, during a period of rapid urbanization. A sharp peak in Cu, Cr, Cd, and Ni concentrations in 1970 is related to industrial discharges in the Still Creek area at the time. Lead has decreased over the past 20 years in lake, stream, and street sediments as a result of the removal of the Pb additive, TEL, from gasoline. During this time, Zn, Cu, Mn, and Hg increased in stream sediments by 45 , 81, 130, and 290 percent respectively. Land use changes since 1973 have been small compared to demographic and traffic changes. Lake sediment contaminant profiles and spatial patterns of stream and street sediment contamination indicate that traffic contributes a large proportion of the Pb, Cu, and Zn loading to the watershed. The large Mn increases in stream sediments since 1973 may be related to in-stream chemical transformations, possibly resulting from usage of the gasoline additive, MMT. Increases in stream sediment Hg levels may be related to point-source emissions originating outside the watershed. Permeable land cover in the upland areas has mitigated some of the effects of nonpoint source pollution generated in more densely populated lower river reaches and has contributed to a relatively healthy aquatic habitat in the eastern region of the watershed. Much of the recent reduction in permeable land cover has occurred in these upland areas.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.444
Threshold uncertainty score0.958

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.200
Teacher spread0.186 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2009
Admission routes1
Has abstractyes

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