MétaCan
Menu
Back to cohort
Record W2492831026

Surface characteristics of chemically modified newsprint fibers determined by inverse gas chromatography

2007· article· en· W2492831026 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueWood and Fiber Science (Society of Wood Science and Technology) · 2007
Typearticle
Languageen
FieldChemistry
TopicAdsorption, diffusion, and thermodynamic properties of materials
Canadian institutionsUniversity of Toronto
FundersUniversity of Toronto
KeywordsInverse gas chromatographyNewsprintPhthalic anhydrideDyeingPolypropyleneAdsorptionPolymer chemistrySurface modificationChemistryFourier transform infrared spectroscopyMaterials scienceOrganic chemistryChemical engineeringCelluloseCatalysisPhysical chemistry
DOInot available

Abstract

fetched live from OpenAlex

The surfacc characteristics of trcated waste newsprint fibers were investigated using inverse gas chromatography (IGC).The surfaces of waste newsprint fibers were modified with y-aminopropyltriethoxysilanc, dichlorodiethylsilane (DCS), phthalic anhydride (PA), and maleated polypropylene.The el'fcctivene\s of these surface treatments was monitored tly the IGC adsorption curves using n-alkanes and acid-base probes.The empirical acid (K,,) and balje (K,,) characteristics (i.e., electron donor1 acceptor abilities) of untreated and trcated newsprint fibers were determined using Schultz's method and were correlated with the surface chemical compositions determined from X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy.The results indicated that the surface of untreated newsprint tibers had an acidic characteristic due to the electron acceptor character of the hydroxyl protons.The newsprint fibers reacted with phthalic anhydride or nialcated polypropylene also exhibited an acidic surface hchavior attributed to pen~dent carboxylic groups.Dichlorodiethylsilane produced a strong acidic surface attributed to the highly elcctronegative nature of the chlorine atoms of dichlorodiethylsilane.Howevel-, when the fibers were reacted with y-arninopropyltriethoxysilane, the basic characteristic (electron donor ability) of the fiber surfacc was increased, presumably by the prescnce of attached amino groups.k'ryrtords: Acid-base properties.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesScience and technology studies
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score0.994

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.009
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.211
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it