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Record W2508316509 · doi:10.1002/9781119234463.ch9

Nanoparticles Seeded Geopolymers

2016· other· en· W2508316509 on OpenAlexaff
Matteo Pernechele, Troczynski Tom, Marek Pawlik

Bibliographic record

VenueCeramic transactions /Ceramic transactions · 2016
Typeother
Languageen
FieldEngineering
TopicConcrete and Cement Materials Research
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsGeopolymerMaterials scienceCompressive strengthMicrostructureMetakaolinChemical engineeringComposite materialNanoparticleSeedingNanotechnology

Abstract

fetched live from OpenAlex

The use of different nanoparticles as seeding agents for geopolymeric binders was studied to determine the relations between the type of seeds and the geopolymers setting time, structural reorganization, compressive strength and durability. The hypothesis that seeds can act as templates for the reorganization of metakaoline based geopolymers was tested using zeolites with different crystal structures and chemistry, silica and alumina. The strain induced by high energy ball milling on the nanoparticles was determined by X-ray diffraction and by spectroscopic techniques. The effects of microstrains in the seeds on the geopolymeric reaction kinetics and products were investigated. FTIR and X-ray diffraction provided the short order and long order information needed to characterize the structural reorganization of the geopolymer. SEM imaging was adopted to study the effect of the seeds on the microstructure, in particular the nature of the geopolymer product (dense particulates or homogeneous gel). The fresh and hardened properties of the geopolymers were studied and correlated with the structure and microstructure of the geopolymers. The properties of the seeded geopolymers are explained in terms of the possible interactions between the seeds surface sites and the forming geopolymer matrix. The seeds had no effects during the first hours of reaction, but they affected the properties of the geopolymer at longer time. The zeolites seeds showed the most pronounced effects on the structural reorganization and compressive strength of the geopolymers.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.237
Teacher spread0.226 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2016
Admission routes1
Has abstractyes

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