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Record W2509521820 · doi:10.1021/acs.jpcc.5b02309

Effects of Graphene in Dye-Sensitized Solar Cells Based on Nitrogen-Doped TiO<sub>2</sub> Composite

2015· article· en· W2509521820 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

fundA Canadian funder is recorded on the work.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueThe Journal of Physical Chemistry C · 2015
Typearticle
Languageen
FieldEnergy
TopicTiO2 Photocatalysis and Solar Cells
Canadian institutionsnot available
FundersBayer CanadaMinistry of Knowledge EconomyKumoh National Institute of Technology
KeywordsDye-sensitized solar cellMaterials scienceGrapheneEnergy conversion efficiencyRaman spectroscopyDopingChemical engineeringNanotechnologySpecific surface areaOptoelectronicsElectrolyteChemistryOpticsElectrodeCatalysis

Abstract

fetched live from OpenAlex

Graphene (GR) exhibits impressive photoelectric properties, including a large specific surface area, high charge-carrier mobility, high conductance, and fast electron transfer. In this study, the effect of GR on the performance of dye-sensitized solar cells (DSSCs) was investigated by mixing GR into N-doped TiO 2 photoelectrodes. GR/N-doped TiO 2 (GNT) nanoparticles were prepared using the sol–gel method. After preparation, the presence of GR in the photoelectrodes was confirmed using transmission electron microscopy (TEM), X-ray diffraction (XRD), and Raman spectroscopy analyses. After the addition of GR, the photoelectrodes displayed enhanced dye adsorption properties with lower internal resistances and faster transport times. Accordingly, DSSCs with these photoelectrodes generated high current density with a low electron-recombination rate. The maximum power conversion efficiency of DSSCs with GR/N-doped photoelectrodes was 9.32% with optimized DSSC parameters; this represents an enhancement of approximately 22% over that of DSSCs with N-doped photoelectrodes. The addition of excess GR weakened the crystallization of particles on the surface of photoelectrodes, which resulted in low dye adsorption and decreased efficiency of the DSSCs. In summary, the addition of GR promoted increased dye loading and enhanced DSSC efficiency. The optimal amount of GR for high-efficiency DSSCs was successfully determined in this study.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.010
Threshold uncertainty score0.596

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.206
Teacher spread0.199 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it