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Record W2510909004 · doi:10.1021/acs.iecr.6b02156

Characterization of Modified Phenol Formaldehyde Resole Resins Synthesized in Situ with Various Boron Compounds

2016· article· en· W2510909004 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2016
Typearticle
Languageen
FieldEngineering
TopicEpoxy Resin Curing Processes
Canadian institutionsUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of CanadaNational Forestry and Grassland Administration
KeywordsBoronCuring (chemistry)FormaldehydeThermal stabilityPhenol formaldehyde resinPhenolMaterials scienceSynthetic resinPolymerizationIn situ polymerizationChemical engineeringNuclear chemistryPolymer chemistryChemistryOrganic chemistryComposite materialPolymer

Abstract

fetched live from OpenAlex

In this study, three different boron compounds were used together with alkaline catalyst to synthesize phenol formaldehyde (PF) resole resins in situ. The resin curing behavior, molecular structure, bonding performance, and properties of resin-impregnated wood were investigated. Results showed that boron compound-modified PF resins had a lower degree of polymerization than the control PF resin made in the laboratory. The curing kinetics, molecular structure, and functional groups of the modified resins varied depending on the type of boron compounds used. The thermal stability of cured modified PF resins was slightly lower than that of laboratory-made control PF resin. Boron compound-modified PF resins exhibited dry and wet bonding strengths comparable to the those of the laboratory-made control PF resin. Wood impregnated using modified PF resins had comparable dimensional stability, mechanical properties and improved fire resistance than the wood impregnated using lab made control PF resin regardless the type of boron compounds used.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.904

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.052
GPT teacher head0.274
Teacher spread0.222 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it