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Record W2523285487 · doi:10.1007/s13659-016-0107-5

Prenylated Coumarins from Heracleum stenopterum, Peucedanum praeruptorum, Clausena lansium, and Murraya paniculata

2016· article· en· W2523285487 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueNatural Products and Bioprospecting · 2016
Typearticle
Languageen
FieldAgricultural and Biological Sciences
TopicPlant chemical constituents analysis
Canadian institutionsFrancophone University Association
FundersNational Development and Reform Commission
KeywordsChemistryMurrayaCoumarinRutaceaeStereochemistryPrenylationTraditional medicineBotanyBiologyBiochemistryOrganic chemistryEnzyme

Abstract

fetched live from OpenAlex

Coumarins are typical secondary metabolites accumulated in the families Apiaceae (Umbelliferae) [ 1 ] and Rutaceae [ 2 ]. The widespread incorporation of prenyl units resulted in the structural diversity of coumarins in both families [ 2 ]. Particularly, the genera Heracleum and Peucedanum from Apiaceae can be characterized by the dominance of furanocoumarins [ 3 ] and pyranocoumarins [ 4 ], respectively. Coumarins possessed diverse pharmacological properties, in which the cytotoxic effects were most extensively examined [ 5 ]. As part of a BioBioPha ( http://www.chemlib.cn/ ) objective to assemble a large-scale natural product library valuable in the discovery of new drug leads from nature [ 6 , 7 ], four new prenylated coumarins Fig. 1 , namely 6″- O - β - d -apiofuranosylapterin ( 1 ), 4′- O -isobutyroylpeguangxienin ( 2 ), 6-(3-methyl-2-oxobutyroyl)-7-methoxycoumarin ( 3 ), and 6-hydroxycoumurrayin ( 4 ), were isolated from the ethanol extract of Heracleum stenopterum , Peucedanum praeruptorum , Clausena lansium , and Murraya paniculata , respectively. This paper described the structure elucidation of new coumarins and their cytotoxicity evaluation against five human cancer cell lines.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.624
Threshold uncertainty score0.327

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.176
Teacher spread0.168 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it