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Record W2525654054 · doi:10.1177/026248931002900502

The Supercritical State Paradigm in Thermoplastic Foaming

2010· article· en· W2525654054 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueCellular Polymers · 2010
Typearticle
Languageen
FieldMaterials Science
TopicPolymer Foaming and Composites
Canadian institutionsNational Research Council Canada
Fundersnot available
KeywordsSupercritical fluidMaterials scienceNucleationBlowing agentSupercritical carbon dioxidePolystyreneSpinodal decompositionChemical engineeringPolymerPhase (matter)ThermodynamicsComposite materialOrganic chemistryChemistryPolyurethane

Abstract

fetched live from OpenAlex

“Supercritical” has become automatically and intrinsically associated with “carbon dioxide foaming”, with this combination generally resulting into claimed benefits such as microcellular structure, high cell density and enhanced mechanical properties. However the supercritical state remains accessible to any blowing agents. The newly-introduced hydrofluorocarbons (HFCs), following the ban put on chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) in the polystyrene foam industry, are other examples of foaming agents that are processed under temperature and pressure conditions that belong to the supercritical region. Unfortunately, such unusual conditions have resulted in the past into typical processing difficulties that make the resulting benefits associated to the supercritical state questionable. The supercritical state may not be apparently the panacea usually claimed… and sought for! In this work, density characteristics of supercritical fluids were reviewed and linked to the foam nucleation stage. Foaming experiments using a specific polymercarbon dioxide system were conducted at the vicinity of the critical locus and the sequence leading to phase separation monitored using an ultrasonic technique. The results suggested a phase separation mechanism similar to that of spinodal decomposition. Density fluctuations reported for supercritical fluids close to their critical locus would translate for the foaming process into concentration fluctuations typical of the spinodal decomposition.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.441

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.207
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it