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Record W2549839395 · doi:10.1002/cjce.22621

Synthesis, performance, and mechanism of magnesium‐iron‐aluminum trimetal composite as an adsorbent for fluoride removal in water treatment

2016· article· en· W2549839395 on OpenAlex
Wei Zhao, Yuantao Chen, Wei Zhang, Jian Wang, Chunlian Hu, Wenfang He

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2016
Typearticle
Languageen
FieldEnvironmental Science
TopicFluoride Effects and Removal
Canadian institutionsnot available
Fundersnot available
KeywordsAdsorptionFluorideAqueous solutionFourier transform infrared spectroscopyLangmuir adsorption modelCalcinationInorganic chemistryMaterials scienceComposite numberScanning electron microscopeChemical engineeringChemistryNuclear chemistryCatalysisComposite materialPhysical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract In this study the Mg‐Fe‐Al trimetal composite was successfully synthesized by an easy co‐precipitation method and used as the adsorbent for fluoride removal from aqueous solutions. Synthetic conditions such as Mg/Fe/Al molar ratio and calcination temperature were studied to optimize the adsorbent. The adsorbents were characterized by X‐ray diffraction (XRD), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDS), and Fourier transform infrared (FTIR). Batch adsorption studies were conducted under various conditions, such as different fluoride concentration, contact time, temperature, initial solution pH, and coexisting anions. Results indicated that the adsorbent obtained the maximum adsorption capacity of 92.85 mg/g for fluoride with a Mg/Fe/Al molar ratio of 30:1:4, calcined at 500 °C, at near‐neutral pH and room temperature (25 °C). The adsorption data were fitted well with the Langmuir isotherm model and the pseudo‐first order kinetic model. The adsorption mechanism involved electrostatic interaction on the surface, ion exchange interaction, and reconstruction of original layered structure by rehydration of mixed metal oxides. All results indicated that the Mg‐Fe‐Al trimetal composite can be a very promising material, has potential application in the removal of fluoride in water treatment, and has positive effects on human health.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.009
Threshold uncertainty score0.234

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.175
Teacher spread0.171 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it