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Record W2564280747 · doi:10.1002/masy.201600077

Sensor Array for Volatile Organic Compounds Based on Doped Poly (2,5‐dimethyl aniline)

2016· article· en· W2564280747 on OpenAlexaff
Katherine M. E. Stewart, Alexander Penlidis

Bibliographic record

VenueMacromolecular Symposia · 2016
Typearticle
Languageen
FieldEngineering
TopicAdvanced Chemical Sensor Technologies
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsAnalyteAnilineMethanolAcetoneBenzeneFormaldehydeAcetaldehydeVolatile organic compoundSensor arraySelectivityMaterials scienceNon-blocking I/OChemistryAnalytical Chemistry (journal)Organic chemistryEthanolChromatography

Abstract

fetched live from OpenAlex

Summary A sensor array containing five different sensing materials has been created that is able to distinguish between six different volatile organic compounds (VOCs) at an analyte concentration of 5 ppm. While none of the sensing materials, poly (2,5‐dimethyl aniline) (P25DMA) and P25DMA doped with four different metal oxide nanoparticles (Al­ 2 O 3 , NiO, TiO 2 , and ZnO), were selective towards any single analyte on their own, through the use of a filtering algorithm, this partial selectivity was exploited. Principal component analysis (PCA) was used as that a filtering algorithm, which was able to separate the responses from the sensing materials and identify six different gas analytes (acetaldehyde, acetone, benzene, ethanol, formaldehyde, and methanol). Both unknown gas analytes and a gas mixture were evaluated to determine the effectiveness of this sensor array.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.522
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.208
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2016
Admission routes1
Has abstractyes

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