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Record W2586374729 · doi:10.15244/pjoes/64310

Investigating the Influence of Some EnvironmentalFactors on the Stability of Paracetamol,Naproxen, and Diclofenac in SimulatedNatural Conditions

2017· article· en· W2586374729 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

aboutThe title or abstract carries a Canadian signal from the geographic lexicon.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenuePolish Journal of Environmental Studies · 2017
Typearticle
Languageen
FieldChemistry
TopicAnalytical Chemistry and Chromatography
Canadian institutionsnot available
Fundersnot available
KeywordsNaproxenDiclofenacNatural (archaeology)Environmental scienceStability (learning theory)Environmental chemistryChemistryMedicineGeologyComputer science

Abstract

fetched live from OpenAlex

Many factors influence the persistence of traces of pharmaceuticals in aqueous environments. Most important are the intensity of light and the presence of inorganic ions as well as organic matter. We studied the impact of some environmental factors (humic acids, NO<sub>3</sub><sup>-</sup> and NO<sub>2</sub><sup>-</sup> ions, solar light intensity, and ambient pH) on the stability and kinetics of photo-reactions of paracetamol, naproxen, and diclofenac. It was stated that paracetamol was photoresistant, while naproxen and diclofenac were photoliable. An addition of NO<sub>3</sub><sup>-</sup> and NO<sub>2</sub><sup>-</sup> ions or humic acid strongly inhibited photodecomposition of paracetamol. Their presence in the solution of naproxen slowed down its decomposition, while in the case of diclofenac their influence on the kinetics of the photoreaction was neglected. The effect of the presence of the natural matrix on the photoreaction of the studied pharmaceuticals was checked. The influence of certified reference material – a water sample from the Grand River (Canada) and a sample of treated municipal waste – was examined. We observed that the matrix created by treated municipal waste acted as a photo-sensitizer. Its presence in solution accelerated the photodecomposition of all studied compounds.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesScience and technology studies
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.021
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.003
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.029
GPT teacher head0.274
Teacher spread0.246 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it