Biogenic Emissions and Nocturnal Ozone Depletion Events at the Amphitrite Point Observatory on Vancouver Island
Bibliographic record
Abstract
Routine monitoring stations on the west coast of North America serve to monitor baseline levels of criteria pollutants such as ozone (O3) arriving from the Pacific Ocean. In Canada, the Amphitrite Point Observatory (APO) on Vancouver Island has been added to this network to provide regional baseline measurements. In 2014, McKendry, I. G., Christensen, E., Schiller, C., Vingarzan, R., Macdonald, A. M., & Li, Y. (2014) reported frequent nocturnal O3 depletion events (ODEs) at APO that generally correlated with alongshore winds, elevated concentrations of carbon dioxide (CO2), and stable boundary layer conditions but the cause (causes) for this remains (remain) unclear.This manuscript presents results from the Ozone-depleting Reactions in a Coastal Atmosphere (ORCA) campaign, which took place in July 2015 to further investigate ODEs at APO. In addition to the long-term measurements at the site (e.g., CO2 and O3 mixing ratios), abundances of biogenic volatile organic compounds (BVOC) and aerosol size distributions were quantified. On the majority of measurement nights, ODEs were observed and characterized by a simultaneous increase in CO2 and BVOC abundances, in particular of limonene, a terpene 2.5 times more reactive with respect to oxidation by O3 than other monoterpenes.Back trajectory calculations showed that ODEs occurred mainly in air masses originating from the west-northwest where the air would have travelled parallel to the coastline and above kelp forests. Head-space analyses of seaweed samples showed that bull kelp is a source of gas-phase limonene, consistent with its high relative abundance in air masses from the west-northwest sector. However, the enhanced terpene and CO2 content showed that the air likely also came in contact with terrestrial vegetation via mesoscale transport phenomena (such as slope flows and land–sea breeze circulations) that were generally poorly captured by the back trajectories. The absence of aerosol growth during ODEs indicates that dry deposition is likely the primary O3 loss mechanism.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.002 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".