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Record W2613838852 · doi:10.1002/cjce.22888

Basic rules of NO oxidation by Fe<sup>2+</sup>/H<sub>2</sub>O<sub>2</sub>/AA directional decomposition system

2017· article· en· W2613838852 on OpenAlexvenueno aff
Haiqian Zhao, Xing-cun Gao, Chenghao Liu, Zhonghua Wang, Hanbing Qi

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2017
Typearticle
Languageen
FieldEngineering
TopicIndustrial Gas Emission Control
Canadian institutionsnot available
FundersNatural Science Foundation of Heilongjiang ProvinceNational Natural Science Foundation of China
KeywordsOxidizing agentFlue gasDecompositionChemistryAtmospheric temperature rangeVolumetric flow rateAnalytical Chemistry (journal)ThermodynamicsEnvironmental chemistryOrganic chemistryPhysics

Abstract

fetched live from OpenAlex

Abstract Basic rules of NO oxidation by a Fe2+/H2O2/AA directional decomposition system were researched based on the technical background of flue gas NOx removal. Effects of gas‐liquid interfacial area, main gas, and solution parameters on NO oxidation efficiency (η) were analyzed. The results showed that adequate contact area was the precondition for high η by a Fe2+/H2O2/AA system. η decreased with the increase in NO concentration, which illustrated that this method would be efficient in oxidizing NO at a low concentration. η tended to decrease linearly with the growth in gas flow, however, the NO oxidation rate (v) rose with the increase in NO concentration and gas flow. η increased with the initial concentrations of H2O2 and Fe2+, but the amplitude decreased. Controlling the initial concentrations of H2O2 and Fe2+ to achieve reasonable synergies between generation rate and consumption rate of ·OH could weaken the invalid consumption of reactants. η increased with the increase in temperature in the range 30–60 °C, but it nearly did not change with temperature after 60 °C. This oxidation technology and the traditional wet flue gas desulphurization technology exhibited temperature synergy. Under typical pH of wet desulphurization, η and H2O2 consumption rate did not change obviously.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.186
Teacher spread0.179 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2017
Admission routes1
Has abstractyes

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