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Record W2615436293 · doi:10.1021/acs.jpcc.7b02454

Pt Thin Films with Nanometer-Sized Terraces of (100) Orientation

2017· article· en· W2615436293 on OpenAlexafffund
Nicolas Sacré, Gregor Hufnagel, Jules Galipaud, Erwan Bertin, Syed Ali Hassan, Matteo Duca, Lionel Roué, Andréas Ruediger, Sébastien Garbarino, Daniel Guay

Bibliographic record

VenueThe Journal of Physical Chemistry C · 2017
Typearticle
Languageen
FieldEnergy
TopicElectrocatalysts for Energy Conversion
Canadian institutionsInstitut National de la Recherche Scientifique
FundersNatural Sciences and Engineering Research Council of CanadaCanada Research Chairs
KeywordsEpitaxyMaterials scienceThin filmSubstrate (aquarium)DiffractionDeposition (geology)Pulsed laser depositionNanometreCrystallographyAnalytical Chemistry (journal)NanotechnologyChemistryOpticsLayer (electronics)Composite material

Abstract

fetched live from OpenAlex

Pulsed laser deposition was used to grow thin layers of Pt on (001)-oriented MgO substrate. The deposition temperature was varied from −25 to 600 °C, and the film thickness was varied from ca. 7 to 45 nm. The crystalline quality, orientation, and epitaxial relationship of Pt thin films on (001)-oriented MgO substrate were investigated by atomic force microscopy and X-ray diffraction as well as through electrochemical probe reactions that are sensitive to the surface crystallographic orientations (H adsorption/desorption) and the width of the (100) terrace (NH 3 electro-oxidation reaction). All thin (7 nm thick) Pt films exhibit only one diffraction peak (the (001) peak) and a 4-fold in-plane symmetry, indicating epitaxial growth is achieved independently of the deposition temperature. Moreover, the pole figure indicates that all films exhibit a Pt(001)[010]//[010](001)MgO cube-on-cube epitaxial relationship, which is consistent with the AFM images. The films are prepared with nearly 60% of (100) sites, and the maximum width of the (100) terraces is nine atomic rows, attained at 325 °C.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.245
Teacher spread0.236 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2017
Admission routes2
Has abstractyes

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Same venueThe Journal of Physical Chemistry CSame topicElectrocatalysts for Energy ConversionFrench-language works237,207