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Record W2622769397 · doi:10.1021/acssuschemeng.7b01378

Ecofriendly Mechanochemical Extraction of Bioactive Compounds from Plants with Deep Eutectic Solvents

2017· article· en· W2622769397 on OpenAlex
Man Wang, Jiaqin Wang, Yanying Zhou, Mingyue Zhang, Qian Xia, Wentao Bi, David D. Y. Chen

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueACS Sustainable Chemistry & Engineering · 2017
Typearticle
Languageen
FieldChemical Engineering
TopicIonic liquids properties and applications
Canadian institutionsUniversity of British Columbia
FundersPriority Academic Program Development of Jiangsu Higher Education InstitutionsMinistry of Education of the People's Republic of ChinaNational Natural Science Foundation of China
KeywordsExtraction (chemistry)Eutectic systemChromatographyChemistryMass spectrometryDetection limitOrganic chemistry

Abstract

fetched live from OpenAlex

A fast, highly efficient, and ecofriendly extraction method using deep eutectic solvents (DESs) for mechanochemical extraction (MCE) was developed to extract bioactive compounds from plants. Tea leaves containing bioactive compounds such as alkaloids, flavonoids, and catechins were used to evaluate this method. Dozens of DESs and DESs/water mixtures were systematically studied and optimized to select optimized extraction conditions. The results showed that the extractions can be completed within 20 s. Moreover, the developed extraction method is more ecofriendly, faster, gentler, and more efficient than conventional methods. For many compounds, we could simply use the described method without optimization. On the other hand, the target compounds were extracted with various interferences because of the wide ranging high extraction efficiency. Ultrahigh performance liquid chromatography coupled with high-resolution mass spectrometry was therefore used for qualitative and quantitative analysis to characterize the efficiency for individual compounds. To avoid the negative effect of DESs on chromatographic separation, the analytical performances of this method, including reproducibility (RSD, n = 5), correlation of determination ( r 2 ), and the limit of detection, were determined.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.024
Threshold uncertainty score0.996

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.217
Teacher spread0.210 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it