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The Existence of Two Types of Colloidal Solutions of Molecules Fullerene C60

2015· article· en· W2624757547 on OpenAlex
D. V. Schur, S. Yu. Zaginaichenko, Т. Н. Везироглу, А. Везироглу, М. Т. Габдуллин

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueJournal of Applied Solution Chemistry and Modeling · 2015
Typearticle
Languageen
FieldChemistry
TopicFullerene Chemistry and Applications
Canadian institutionsnot available
Fundersnot available
KeywordsFullereneSolubilityMoleculeSolventChemistryHildebrand solubility parameterFullerene chemistryThermodynamicsOrganic chemistryPhysics

Abstract

fetched live from OpenAlex

The last thirty years scientists carried out an active search of universal parameter of solvent C60 for predicting the solubility of fullerenes. However, this parameter was not found up to these days. In this paper it has been found an explanation of the impossibility of detection of such parameter. In present paper the features of the solubility of fullerene C60 molecules in nonpolar solvents have been studied. The molecule state diagram of the fullerene С60 molecules in solution at temperatures 265+308 K and pressure range 1+100 MPa indicating the existence field of β and γ-modifications, has been constructed. Moreover, it has been shown that in the solutions of fullerenes C60 in the γ-state the solubility decreases with a rise in temperature since the chemical activity of fullerene molecule increases. For this reason during extraction procedure the temperature rise causes the value of extraction rate to increase, but solubility – to decrease, i.e. to diminish the concentration of fullerenes molecules in the solvent volume.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.030
Threshold uncertainty score0.456

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.055
GPT teacher head0.279
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it