Study of Ion Speciation of CO<sub>2</sub> Absorption into Aqueous 1-Dimethylamino-2-propanol Solution Using the NMR Technique
Bibliographic record
Abstract
In this work, the speciation (i.e., 1DMA2P molecule as well as 1DMA2PH +, HCO 3 –, and CO 3 2– ions) for the CO 2 reactive absorption of CO 2 in aqueous 1-dimethylamino-2-propanol solution (i.e., into a 1DMA2P–H 2 O–CO 2 system) was studied using the 13 C nulcear magnetic resonance (NMR) technique at a temperature of 301 K over the 1DMA2P concentration range of 0.5–2.0 mol/L and CO 2 loading range of 0–1.0 mol CO 2 /mol amine. Also, in addition to other material conservation laws, a new criterion for selection of the protonation calibration curves, the charge balance of the 1DMA2P–H 2 O–CO 2 system, was added in order to generate results with better accuracy. In addition, the equilibrium constants, K 1 and K 5, were also obtained using the NMR technique, which had good agreement with those from other works with absolute average deviations of 2.2% and 3.5%, respectively.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".