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Record W2761321363 · doi:10.1021/acsami.7b11628

Moving Beyond Boron-Based Substituents To Achieve Phosphorescence in Tellurophenes

2017· article· en· W2761321363 on OpenAlexafffund
William Torres Delgado, Christina A. Braun, Michael P. Boone, Olena Shynkaruk, Yanyu Qi, Robert McDonald, Michael J. Ferguson, Przemysław Data, Shawan K. C. Almeida, Inara de Aguiar, Gabriel L. C. de Souza, Alex Brown, Gang He, Eric Rivard

Bibliographic record

VenueACS Applied Materials & Interfaces · 2017
Typearticle
Languageen
FieldMaterials Science
TopicLuminescence and Fluorescent Materials
Canadian institutionsUniversity of Alberta
FundersNatural Sciences and Engineering Research Council of CanadaHorizon 2020 Framework ProgrammeCanada Foundation for InnovationKillam TrustsAlexander von Humboldt-Stiftung
KeywordsPhosphorescenceQuenching (fluorescence)PhosphorBoronPhotochemistryLuminescenceTelluriumArylMaterials scienceOxygenPersistent luminescenceSolid-stateFluorescenceOptoelectronicsChemistryPhysical chemistryOrganic chemistryPhysicsThermoluminescenceOptics

Abstract

fetched live from OpenAlex

(4BTe), oxygen-mediated quenching of phosphorescence is an important contributor to the lack of emission in solution (when exposed to air); thus, this system displays aggregation-enhanced emission (AEE). These discoveries should facilitate the future design of color tunable tellurium-based luminogens.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Scholarly communication, Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0020.001
Open science0.0020.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.260
Teacher spread0.247 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations49
Published2017
Admission routes2
Has abstractyes

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