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Record W2762522373 · doi:10.1002/slct.201701951

Nitrogen‐Doped Graphene Nanosheets/S Composites as Cathode in Room‐Temperature Sodium‐Sulfur Batteries

2017· article· en· W2762522373 on OpenAlexaff
Yong Hao, Xifei Li, Xueliang Sun, Chunlei Wang

Bibliographic record

VenueChemistrySelect · 2017
Typearticle
Languageen
FieldEngineering
TopicAdvanced Battery Materials and Technologies
Canadian institutionsWestern University
FundersNatural Environment Research CouncilJilin UniversityNational Science Foundation
KeywordsGrapheneMaterials scienceNanocompositeCathodeSulfurElectrochemistryComposite numberChemical engineeringIntercalation (chemistry)Composite materialEnergy storageElectrodeNanotechnologyInorganic chemistryChemistry

Abstract

fetched live from OpenAlex

Abstract Room‐temperature sodium‐sulfur (RT Na−S) batteries have gained increasing attention from energy storage community in recent years. In this work, homogeneous nitrogen‐doped graphene nanosheets/sulfur (NGNS/S) nanocomposites, synthesized using chemical reaction‐deposition method and low temperature heat treatment, were studied as active cathode materials for RT Na−S batteries. Different loading composites with 86%, 65%, 45% and 25% gamma‐S 8 have been electrochemically evaluated, respectively, and compared with two control electrodes of NGNS and S. It was found that the NGNS/S composite with 25% S loading exhibited the best electrochemical performance with specific capacities of 212 and 136 mAh g −1 in the 1st and 10th cycles, respectively. The enhanced electrochemical performance of NGNS/S nanocomposite is mainly attributed to the improved kinetics due to the NGNS conductive network and easier intercalation of Na + into expanded NGNS layers due to the addition of S within the graphene layers. In addition, the composite with 25% S loading shows higher surface area and complete reaction with product of Na 2 S, which likely contributes to the improved energy capacity.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.223
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations44
Published2017
Admission routes1
Has abstractyes

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