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Record W2762813143 · doi:10.1002/cjce.23044

Short‐chain esters enriched biofuel obtained from vegetable oil using molecular distillation

2017· article· en· W2762813143 on OpenAlexvenueno aff
Vanessa Fernandes de Oliveira, Expedito J. S. Parente, Célio L. Cavalcante, F. Murilo T. Luna

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2017
Typearticle
Languageen
FieldEngineering
TopicBiodiesel Production and Applications
Canadian institutionsnot available
FundersPetrobrasConselho Nacional de Desenvolvimento Científico e Tecnológico
KeywordsKeroseneJet fuelAviation fuelDistillationBiofuelRaw materialGasolineVacuum distillationEnvironmental scienceFossil fuelFreezing pointContext (archaeology)Waste managementPulp and paper industryChemistryOrganic chemistryEngineering

Abstract

fetched live from OpenAlex

Abstract Aviation fuels used in gas‐turbine engine powered aircraft are mainly obtained from the distillation of mineral oil. These jet fuel molecules present carbon chain length of C 8 to C 16 in the same range of fossil kerosene and have high calorific values and a great cold behaviour. With the increase in consumption of jet fuels, it has become extremely important to develop alternative fuels with adequate properties that could be capable of fulfilling the aviation industry requirements. In this context, aviation alternative fuel originated from sustainable raw materials must meet a set of safety requirements and should exhibit similar physicochemical properties to mineral kerosene. In this study the production of a short‐chain esters enriched biofuel using molecular distillation of FAME obtained from babassu oil was evaluated. Operational conditions were assessed to obtain high mass yields and high ester content in the carbon chain length range of kerosene. A fuel with properties close to those of aviation biofuels was obtained at 140 °C. At this temperature, more than 80 % of the esters in the product composition were within the desired range and there was a mass recovery higher than 88 %. In addition, the short‐chain esters enriched biofuel was blended with fossil kerosene at different concentrations and its properties were analyzed in order to study the effects of the gradual addition of this biofuel stream to commercial aviation kerosene. Density, heating value, freezing temperature, and pour point were evaluated. A mixture up to 6.0 % g/g accomplished the specification limits established by ASTM D1655.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.422
Threshold uncertainty score0.429

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.207
Teacher spread0.192 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations21
Published2017
Admission routes1
Has abstractyes

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