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Record W2769142255 · doi:10.1002/9783527651733.ch19

Metal‐Catalyzed Multicomponent Reactions

2017· other· en· W2769142255 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

Venuenot available
Typeother
Languageen
FieldChemistry
TopicMulticomponent Synthesis of Heterocycles
Canadian institutionsMcGill University
Fundersnot available
KeywordsCycloadditionCatalysisCarbonylationChemistryTransition metalCarbon monoxideCoupling reactionMetalComputational chemistryMetal carbonylCombinatorial chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Multicomponent coupling reactions have become of growing importance in the design of efficient synthetic methods. This chapter highlights some of the important general classes of the metal-catalyzed multicomponent reactions, with a focus upon those that use building blocks that are all, or nearly all, readily available, and therefore of potential industrial relevance. A common approach to metal-catalyzed multicomponent reactions involves exploiting carbonylation chemistry. The incorporation of carbon monoxide into products often involves a multicomponent reaction, where the carbonyl unit in the product is linked to two separate fragments. Transition metal-catalyzed multicomponent reactions have been employed to build up products that are themselves intermediates in subsequent, non-metal based reactions. While examples of these reactions are described above, one general manifold involves generating substrates for cycloaddition reactions, such as 1,3-dipoles for use in dipolar cycloaddition reactions. The transition metal catalyzed formation of 1,3-dipoles has been applied to multicomponent syntheses in a number of directions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.558
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0500.003

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.032
GPT teacher head0.281
Teacher spread0.249 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Quick stats

Citations1
Published2017
Admission routes1
Has abstractyes

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