2,3,5,6-Tetra(1<i>H</i>-tetrazol-5-yl)pyrazine: A Thermally Stable Nitrogen-Rich Energetic Material
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
A synthetic protocol was developed to create a unique nitrogen-rich (71.58% N) energetic material, namely, 2,3,5,6-tetra(1 H -tetrazol-5-yl)pyrazine (H 4 TTP). This compound was prepared using a convenient and straightforward method of synthesis and shows useful energetic properties such as detonation velocity ( V C-J = 8655 m s –1 ), detonation pressure ( p C-J = 28.0 GPa), and high temperature of decomposition ( T dec = 260 °C). H 4 TTP was isolated and characterized using mass spectrometry, multinuclear ( 1 H, 13 C) NMR spectroscopy, and vibrational spectroscopy (IR, Raman). The molecular structure was determined via single-crystal X-ray diffraction. High nitrogen content and relative planarity of the molecule, along with the attained properties such as hydrolytic stability, high thermal stability, density, detonation velocity, and its facile synthesis, make H 4 TTP a highly interesting energetic material.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.005 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it