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Record W2791655871 · doi:10.1002/pen.24837

Understanding the morphology formation and properties of polyamide 6 and bio‐based poly(trimethylene terephthalate) blends

2018· article· en· W2791655871 on OpenAlexafffund
Amandine Codou, Manjusri Misra, Amar K. Mohanty

Bibliographic record

VenuePolymer Engineering and Science · 2018
Typearticle
Languageen
FieldMaterials Science
Topicbiodegradable polymer synthesis and properties
Canadian institutionsUniversity of Guelph
FundersNatural Sciences and Engineering Research Council of CanadaOntario Ministry of Agriculture, Food and Rural Affairs
KeywordsMaterials sciencePolyamideExtrusionMorphology (biology)Scanning electron microscopeRheologyComposite materialPolymer blendSurface tensionPolymerChemical engineeringCopolymer

Abstract

fetched live from OpenAlex

The influence of processing conditions on bio‐based poly (trimethylene terephthalate) (PTT) and polyamide 6 (PA6) blends via twin‐screw extrusion was successfully investigated, bringing new knowledge on the physical interactions between two widely used thermoplastics. A 50/50 wt% blend ratio was selected since it is characteristic of its unpredictable morphology and as such can highlight the behavior of the PTT/PA6 system in general, relevant for all blend ratios. Moreover, those materials are the two most used fibers in carpet industries and this blend presents a possible reality for carpet recycling via melt processing. The effects of the processing conditions on blend morphology were highlighted on the material surface by atomic force microscopy (AFM), and in the bulk by scanning electron microscopy (SEM) after solvent etching of the PA6 phase. The domain size was strongly influenced by the processing temperature used, which was explained by existing theories of blending via measurement of rheology and interfacial tension. The mechanical properties highlighted the interest of controlled morphology through adaptation of the processing parameters for end‐product applications. POLYM. ENG. SCI., 58:2210–2218, 2018. © 2018 Society of Plastics Engineers

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.038
Threshold uncertainty score0.520

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.057
GPT teacher head0.224
Teacher spread0.168 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2018
Admission routes2
Has abstractyes

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