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Record W2792219853 · doi:10.1002/pen.24844

Tuning the mechanical and dielectric properties of clay‐containing thermoplastic elastomer nanocomposites

2018· article· en· W2792219853 on OpenAlexafffund
Emna Helal, Leice G. Amurin, Danilo J. Carastan, Rogério Ramos de Sousa, Éric David, M.F. Frechétte, Nicole R. Demarquette

Bibliographic record

VenuePolymer Engineering and Science · 2018
Typearticle
Languageen
FieldMaterials Science
TopicPolymer Nanocomposites and Properties
Canadian institutionsHydro-QuébecÉcole de Technologie Supérieure
FundersConselho Nacional de Desenvolvimento Científico e TecnológicoNatural Sciences and Engineering Research Council of CanadaCoordenação de Aperfeiçoamento de Pessoal de Nível SuperiorFundação de Amparo à Pesquisa do Estado de São Paulo
KeywordsMaterials scienceComposite materialNanocompositeThermoplastic elastomerIzod impact strength testElastomerPolystyreneThermoplasticIsotropyStiffnessCopolymerUltimate tensile strengthPolymer

Abstract

fetched live from OpenAlex

In this study, the mechanical strength and the AC short term breakdown strength of polystyrene‐ b ‐poly(ethylene‐ co ‐butylene)‐ b ‐polystyrene (SEBS) thermoplastic elastomer clay‐containing nanocomposites have been investigated as function of their morphologies. The SEBS/clay nanocomposites with tailored morphologies were prepared previously by different processing techniques. They featured different orientations of clay platelets as well as polystyrene (PS) block nanodomains, namely: isotropic, oriented, and partially oriented morphologies. In unfilled SEBS matrices, the mechanical strength was mainly tuned by the orientation of PS block nanodomains. A good correlation between the dielectric breakdown strength and the mechanical stiffness was observed overall: the higher the mechanical strength was, the higher the breakdown strength was. In the nanocomposites, the orientation of clay platelets as well as the degree of order and the characteristic sizes of the block copolymer domains were seen to affect strongly the breakdown strength behavior in addition to the mechanical strength. In particular, the partially oriented morphology achieved by film blowing extrusion exhibited the maximum increase of the breakdown strength by 25% with optimized mechanical stiffness evaluated between that of the oriented morphology as a lower limit and that of the isotropic morphology as an upper limit. POLYM. ENG. SCI., 58:E174–E181, 2018. © 2018 Society of Plastics Engineers

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.034
Threshold uncertainty score0.326

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.202
Teacher spread0.191 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2018
Admission routes2
Has abstractyes

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