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Record W2793164271 · doi:10.1002/cjce.23192

Photo‐catalytic degradation of formaldehyde using nitrogen‐doped TiO<sub>2</sub> nano‐photocatalyst: Statistical design with response surface methodology (RSM)

2018· article· en· W2793164271 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2018
Typearticle
Languageen
FieldEnvironmental Science
TopicWater Quality Monitoring and Analysis
Canadian institutionsnot available
Fundersnot available
KeywordsFormaldehydePhotocatalysisResponse surface methodologyCatalysisMaterials scienceCentral composite designFourier transform infrared spectroscopyDegradation (telecommunications)Nuclear chemistryNano-NitrogenNanoparticleChemical engineeringSpectrophotometryDopingChemistryNanotechnologyComposite materialChromatographyOrganic chemistryOptoelectronics

Abstract

fetched live from OpenAlex

Abstract Formaldehyde is considered as a common pollutant in industrial wastewaters requiring removal techniques designed to reduce its harmful effects due to distribution in the environment. In this study, TiO 2 nanoparticles are modified through nitrogen doping by sol‐gel technique and their photo‐catalytic performance for formaldehyde degradation is studied under UV and solar irradiation. Various characterization techniques such as: PSA, FTIR, XRD, and SEM are performed on the synthesized nano‐photocatalyst with a ∼20 nm average size. The significance of parameters such as initial formaldehyde concentration, catalyst molar ratio N/Ti, pH, and removal time under UV and solar radiation are assessed using response surface methodology based on central composite design. Formaldehyde removal was measured as a function of irradiation time using UV‐Visible spectrophotometry. The results show that the maximum formaldehyde removal at optimal conditions (pH = 5 for 400 ppm initial formaldehyde concentration) by nitrogen‐doped TiO 2 is 64.02 % under solar and 60.15 % under UV radiation suggesting it as an effective photo‐catalyst for formaldehyde removal.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.034
Threshold uncertainty score0.433

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.045
GPT teacher head0.250
Teacher spread0.205 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it