Bibliographic record
Abstract
By virtue of regio-and geometric isomers, functionalized double-decker silsesquioxanes (DDSQ) may offer unique access to silsesquioxane-based hybrid materials with multifaceted performance characteristics. Analytical methods were as used to separate cis and trans isomers of various DDSQ with polar as well as nonpolar moieties. Solubility was fitted to the Schrder-van Laar equation with activity coefficients determined using the NRTL model by adjusting binary interaction parameters. For a given DDSQ compound, the variances in solubility between cis and trans isomers depend on differences in thermal properties. cis and trans isomers binary phase diagrams of DDSQs were also developed to examine the influence of the regioisomer (meta-or para-) and the nonactive organic moiety coupled on the D-silicon. DDSQ compounds with a methyl moiety exhibited eutectic phase diagrams. Their trans isomers were higher melting and exhibited larger packing density. Cyclohexyl DDSQ exhibited an isomorphic phase diagram, attributed to cyclohexyl being more similar in size to the phenyl moieties. Changing from para-to meta-aminophenyl shifted the solid-liquid equilibrium further from ideal, with decreased activity coefficients.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".