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Record W2803970994 · doi:10.1021/acs.jced.8b00208

Reply to “Comment on ‘Determination and Correlation of Dipyridamole <i>p</i>-Toluene Sulfonate Solubility in Seven Alcohol Solvents and Three Binary Solvents’”

2018· article· en· W2803970994 on OpenAlexfundno aff
Mengya Li, Shiyuan Liu, Si Li, Yang Yang, Yingdan Cui, Junbo Gong

Bibliographic record

VenueJournal of Chemical & Engineering Data · 2018
Typearticle
Languageen
FieldMaterials Science
TopicCrystallization and Solubility Studies
Canadian institutionsnot available
FundersNational Natural Science Foundation of ChinaMinistry of Science and Technology of the People's Republic of ChinaCNIB
KeywordsChemistryTolueneSolubilityMole fractionSulfonateBinary numberAlcoholThermodynamicsAnalytical Chemistry (journal)Physical chemistryOrganic chemistryPhysics

Abstract

fetched live from OpenAlex

The Comment on “Determination and Correlation of Dipyridamole p-Toluene Sulfonate Solubility in Seven Alcohol Solvents and Three Binary Solvents” is appreciated. According to the comments, we make a deep analysis and discussion of our article again. The reason for large deviations between the back-calculated value presented in our paper and the back-calculated value calculated by Acree is that we mixed up the coefficients calculated by two programs and the wrong Apelblat equation coefficients were submitted in our paper instead of the corrected ones. Therefore, the model parameters of the Apelblat equation and the calculated mole fraction solubilities of dipyridamole p-toluene sulfonate in all solvents at the temperature ranging from 288.15 to 328.15 K were recalculated by the corrected program and show satisfactory correlation results with the experimental values.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.376
Threshold uncertainty score0.368

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.034
GPT teacher head0.289
Teacher spread0.255 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2018
Admission routes1
Has abstractyes

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