Solar Fuels: Tailoring Surface Frustrated Lewis Pairs of In<sub>2</sub>O<sub>3−</sub><i><sub>x</sub></i>(OH)<sub>y</sub> for Gas‐Phase Heterogeneous Photocatalytic Reduction of CO<sub>2</sub> by Isomorphous Substitution of In<sup>3+</sup> with Bi<sup>3+</sup> (Adv. Sci. 6/2018)
Bibliographic record
Abstract
The excited state acidity and basicity of surface frustrated Lewis pairs in oxygen vacancy and hydroxide defect laden BizIn2−zO3−xOHy can be chemically tailored by controlling the level of isomorphous substitution of Bi(III) for In(III). As shown in article number 1700732 by Chandra Veer Singh, Geoffrey A. Ozin, and co-workers, this makes it possible to optimize the catalytic performance of the solar powered reverse water gas shift reaction.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.004 | 0.001 |
| Meta-epidemiology (narrow) | 0.002 | 0.003 |
| Meta-epidemiology (broad) | 0.003 | 0.001 |
| Bibliometrics | 0.003 | 0.010 |
| Science and technology studies | 0.001 | 0.008 |
| Scholarly communication | 0.000 | 0.005 |
| Open science | 0.003 | 0.001 |
| Research integrity | 0.001 | 0.002 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".