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Record W2809048613 · doi:10.1109/tnano.2018.2849264

Cyclic Liquid-Phase Exfoliation of Electrically Conductive Graphene-Derivative Inks

2018· article· en· W2809048613 on OpenAlex
Dogan Sinar, George K. Knopf

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueIEEE Transactions on Nanotechnology · 2018
Typearticle
Languageen
FieldEngineering
TopicNanomaterials and Printing Technologies
Canadian institutionsWestern University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsMaterials scienceInkwellConductive inkGrapheneExfoliation jointElectrical conductorCarboxymethyl celluloseNanotechnologyConductive polymerPolymerScreen printingOptoelectronicsChemical engineeringComposite materialSheet resistanceLayer (electronics)

Abstract

fetched live from OpenAlex

Advances in electrically conductive inks and printing technology have enabled microelectrodes, chemical sensors, wireless radio frequency identification tags, and bioelectronic circuits to be fabricated on mechanically flexible polymers, paper, and bioresorbable silk. Although conductive polymer and metal-based inks have been used to build functional devices, these materials are often expensive and may involve complicated toxic chemical processes. Recent research has demonstrated that graphene (G), and its derivatives, can be used to create water-based conductive inks. In this paper, an environmentally friendly and cost-effective G-based conductive ink is proposed. The ink is created by using a nontoxic hydrophilic cellulose derivative, Carboxymethyl Cellulose (CMC), to facilitate liquid phase exfoliation and stabilization of naturally hydrophobic G sheets in DI water at high concentrations. It is demonstrated that recycling of nonexfoliated material can produce inks at comparable concentrations. Physical dimensions and defect status of exfoliated G sheets are characterized. Inkjet deposition of thin and thick films is achieved using a binary solvent system and electrical performance of resulting films is investigated. Film morphology is shown to be consistent between thin and thick films. Experiments have demonstrated that G-CMC films of <;700 Ω/sq can be inkjet printed without use of dopants or dangerous solvents.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.350
Threshold uncertainty score0.845

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.257
Teacher spread0.242 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it