A novel copper selective sensor based on ion imprinted 2-vinylpyridine polymer
Bibliographic record
Abstract
A novel potentiometric Cu 2+ -selective microsensor has been developed that is based upon ion imprinted 2-vinylpyridine polymer. The polymer was synthesized using Cu(II) ions, 2-vinylpyridine, methacrylic acid, and ethylene glycol dimethacrylate as a template, functional monomer, and cross-linker, respectively. The resultant polymer was used as ionophore to obtain a selective potentiometric response towards Cu(II) ions in the structure of the PVC membrane. The detection limit of the microsensor was determined to be 8.4 × 10 −7 mol/L, and its response time was considerably short (less than 15 s). The prepared microsensor exhibited a near-Nernstian response for Cu(II) ions over the concentration range of 10 −1 to 10 −6 mol/L, with a slope of 28.5 mV per decade over 2 months, and without any considerable divergence in potentials. The microsensor was effectively performed in a pH range between 4.0 and 7.0 and used as an indicator electrode in the potentiometric titration of Cu(II) ions with EDTA. The proposed microsensor has been successfully demonstrated for the determination of copper in a number of environmental water samples. The obtained potentiometric results were in good harmony with the results obtained by the AAS method.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".