Electrochemical Property–Structure Correlation for Ni-Based Layered Na-Ion Cathodes
Bibliographic record
Abstract
A class of Ni-based layered NaxNi0.5Mn0.3Co0.2O2 oxide composites is prepared via a solid-state process. Mixed P-, O-, and P-/O-type phases can be obtained by tuning the Na content and annealing temperature, as demonstrated by structural and chemical characterization. Among these materials, the triphase P2/P′3/O′3-type composite exhibits the best overall electrochemical performance. Specifically, this triphase composite delivers a high specific capacity of 126 mA h g–1 in the potential range of 1.5–4.2 V, high rate capability (∼72% of its initial capacity at a rate of 5 C), and good capacity retention after 100 cycles at 0.5 C. The structural transition mechanism for each phase upon electrochemical cycling is investigated, providing insights into the correlation between electrochemical properties and the crystal structure of Ni-rich layered NaxNi0.5Mn0.3Co0.2O2 oxide composites.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".