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Record W2885710987 · doi:10.1021/acs.jchemed.8b00175

Investigating NO<sub><i>x</i></sub> Concentrations on an Urban University Campus Using Passive Air Samplers and UV–Vis Spectroscopy

2018· article· en· W2885710987 on OpenAlexfundno aff
Cole M. Crosby, Richard A. Maldonado, Ahyun Hong, Ryan Caylor, Kristine L. Kuhn, Matthew E. Wise

Bibliographic record

VenueJournal of Chemical Education · 2018
Typearticle
Languageen
FieldEnvironmental Science
TopicAir Quality Monitoring and Forecasting
Canadian institutionsnot available
FundersConcordia University
KeywordsSpectroscopyEngineering physicsEnvironmental scienceRemote sensingAnalytical Chemistry (journal)Materials scienceEnvironmental chemistryChemistryPhysicsGeography

Abstract

fetched live from OpenAlex

Gas-phase nitrogen oxides are important in the formation of tropospheric ozone. NOx (NO and NO2) as well as tropospheric ozone have been shown to have negative effects on human health. Therefore, accurately measuring NOx concentrations in the atmosphere is important. In this laboratory experience, students measured ambient NOx concentrations using a relatively simple and inexpensive passive sampling/UV–vis spectroscopy technique. The students used two different types of spectrophotometers to determine limits of detection and ambient NOx concentrations. Data demonstrated both spectrometers behaved similarly, proving laboratories utilizing different spectrophotometers could accurately perform the experiment. Although not statistically verified due to the limited number of passive samplers employed in the pilot experiment, measured NOx concentrations were similar to those calculated by a local air quality model (within approximately 50 parts per billion). At the end of the laboratory experience, students compared their measured NO2 concentrations to the United States Environmental Protection Agency’s primary and secondary standard of 53 parts per billion (annual mean). The initial learning goals of the experiment included the following: the successful creation of calibration curves, the determination of spectrophotometer limit of detection, and the calculation of ambient NOx concentrations. The experiment is appropriate for students enrolled in analytical and environmental chemistry courses.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.010
Threshold uncertainty score0.334

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.269
Teacher spread0.251 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2018
Admission routes1
Has abstractyes

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