Synthesis, Charecterization of a New 16 A, S, C-HBPAE-b-PCL Copolymers and the Mechanical Properties of the Copolymer-Cement Composites
Bibliographic record
Abstract
The new 16-Arms, Star, Coil-HBPAE-b-PCL(16 A, S, C-HBPAE-b-PCL) copolymers was synthesized hyperbranched poly amide-ester (HBPAE) as the macroinitiator and epsilon caprolactone (-CL) monomer by using Ring Opening(ROP). Characterisation of the polymers was achieved by FTIR, 1 H NMR GPC, MS, SEM, AFM, TGA, DSC, techniques and MTS Criterion brand 45 model mechanical testing. The new 16 A, S, C-HBPAE-b-PCL-OPC composites containing 16 A, S, C-HBPAE-b-PCL additive were prepared for the purpose of improve of Ordinary Portland Cement(OPC) properties. The compressive strength and the bending resistance tests of the composites were investigated.The cement mortar samples prepared for the experiments were produced in the laboratories of Karadeniz Technical University in accordance with TS EN 196-1, TS EN ISO 15630-1 and TS EN ISO 7500-1 "Cement test methods" standard.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".