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Record W2889853111 · doi:10.1021/acs.est.8b03409

Benefit of Hydrophilicity for Adsorption of Methyl Orange and Electro-Fenton Regeneration of Activated Carbon-Polytetrafluoroethylene Electrodes

2018· article· en· W2889853111 on OpenAlexafffund
Ye Xiao, Josephine M. Hill

Bibliographic record

VenueEnvironmental Science & Technology · 2018
Typearticle
Languageen
FieldEnvironmental Science
TopicAdvanced oxidation water treatment
Canadian institutionsUniversity of Calgary
FundersCanada Research Chairs
KeywordsPolytetrafluoroethyleneAdsorptionActivated carbonMethyl orangeElectrodeOrange (colour)Regeneration (biology)Chemical engineeringMaterials scienceChemistryComposite materialOrganic chemistryPhotocatalysisCatalysis

Abstract

fetched live from OpenAlex

Activated carbon (AC)-polytetrafluoroethylene (PTFE) electrodes were prepared and applied for methyl orange (MO) adsorption and electro-Fenton regeneration. The addition of PTFE to AC significantly decreased the hydrophilicity, which in turn, decreased both the amount of MO adsorbed and the regeneration efficiency. With the minimum amount of binder (a 7:1 mass ratio of AC to binder), the MO adsorption was 176 mg g–1. The amount adsorbed decreased to 23 mg g–1 for the electrode with a 1:1 mass ratio of AC to binder. For these ratios, the regeneration efficiencies were 81% and 49%, respectively. The adsorption kinetics were well fit by a Weber–Morris model. The diffusion rate constants obtained from this model were linearly related to the hydrophilicity of the electrode, i.e., the higher the hydrophilicity the higher the adsorption rate. Based on the results, an adsorption capacity >50 mg g–1 in 8 h with a regeneration efficiency of >70% at cathodic potential of −0.8 V (vs Ag/AgCl) can be obtained if the contact angle of water on the electrodes is lower than 90°.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesScience and technology studies
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.012
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.003
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.228
Teacher spread0.222 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations54
Published2018
Admission routes2
Has abstractyes

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