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Record W2892018314 · doi:10.1002/smll.201803310

Ultrahigh‐Capacity and Long‐Life Lithium–Metal Batteries Enabled by Engineering Carbon Nanofiber–Stabilized Graphene Aerogel Film Host

2018· article· en· W2892018314 on OpenAlex
Changtai Zhao, Chang Yu, Shaofeng Li, Wei Guo, Yang Zhao, Qiang Dong, Xiaoting Lin, Zhongxin Song, Xinyi Tan, Changhong Wang, Matthew Zheng, Xueliang Sun, Jieshan Qiu

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueSmall · 2018
Typearticle
Languageen
FieldEngineering
TopicAdvanced Battery Materials and Technologies
Canadian institutionsWestern University
FundersNational Key Research and Development Program of ChinaCanada Foundation for InnovationNational Natural Science Foundation of ChinaWestern UniversityNatural Sciences and Engineering Research Council of CanadaCanada Excellence Research Chairs, Government of Canada
KeywordsMaterials scienceAerogelGrapheneAnodeOverpotentialCarbon nanofiberCathodeChemical engineeringCarbon fibersLithium (medication)NanofiberNanotechnologyComposite materialElectrochemistryCarbon nanotubeElectrodeComposite numberChemistry

Abstract

fetched live from OpenAlex

Abstract A safe, high‐capacity, and long‐life Li metal anode is highly desired due to recent developments in high‐energy‐density Li–metal batteries. However, there are still rigorous challenges associated with the undesirable formation of Li dendrites, lack of suitable host materials, and unstable chemical interfaces. Herein, a carbon nanofiber‐stabilized graphene aerogel film (G‐CNF film), inspired by constructional engineering, is constructed. As the host material for Li deposition, the G‐CNF film features a large surface area, porous structure, and a robust skeleton that can render low local current density. This allows for dendrite‐free Li deposition and mitigation of problems associated with large volume change. Importantly, the G‐CNF film can keep high Li plating/stripping efficiency at nearly 99% for over 700 h with an areal capacity of 10 mA h cm −2 (the specific capacity up to 2588 mA h g −1 based on the total mass of carbon host and Li metal). The symmetric cells can stably run for more than 1000 h with low voltage hysteresis. The full cell with the LiFePO 4 cathode also delivers enhanced capacity and lowered overpotential. As two‐in‐one host materials for both cathodes and anodes in Li–O 2 batteries, the battery exhibits a capacity of 1.2 mA h cm −2 .

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.176
Teacher spread0.167 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it