Structural characteristics, analytical techniques and interactions with organic contaminants of dissolved organic matter derived from crop straw: a critical review
Bibliographic record
Abstract
Dissolved organic matter (DOM) represents one of the most mobile and reactive organic compounds in an ecosystem and plays an important role in the fate and transport of soil organic pollutants, nutrient cycling and more importantly global climate change. Advances in environment geochemistry in the past two decades have improved our knowledge about the genesis, composition, and structure of DOM, and its effect on the environment. Application of analytical technology, for example UV-visible spectroscopy (UV-Vis), Fourier transform infrared spectroscopy (FTIR), Nuclear magnetic resonance (NMR) spectroscopy, and three-dimensional fluorescence spectroscopy (3D-EEM) have resulted in these advances. At present, crop straw, as a part of energy development strategy, is mainly used for soil amendment, fodder, fertilizer and industrial materials. Moreover, the fermentation and decomposition of straw should be also promoted for ecological agriculture. However, few studies have focused on the structural properties of DOM derived from crop straw in farmland soil. In this article, DOM derived from crop straw, which is abbreviated to "CDOM", presents active physicochemical properties that can affect the migration and bioavailability of organic contaminants (OCs) in terrestrial ecosystems. The objectives of this review paper are: (i) to discuss the structural characteristics, analytical techniques and interactions between CDOM and OCs in farmland soil; (ii) to present a critical analysis of the impact of CDOM on the physicochemical transformation and transport of OCs in farmland soils; (iii) to provide the perspectives in future research. Therefore, the findings obtained from this study can be utilized to evaluate the relations of interactions between CDOM and OCs in agricultural soils, in order to support some suggestions for future development in agricultural waste recycling, buffering of organic pollution, and the effect on the global carbon cycle.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.002 |
| Meta-epidemiology (narrow) | 0.001 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.001 |
| Bibliometrics | 0.004 | 0.004 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.002 |
| Open science | 0.001 | 0.001 |
| Research integrity | 0.001 | 0.001 |
| Insufficient payload (model declined to judge) | 0.002 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".