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Record W2908669408 · doi:10.1515/polyeng-2018-0026

Comparison of two encapsulation systems of UV stabilizers on the UV protection efficiency of wood clear coats

2018· article· en· W2908669408 on OpenAlexaff
Caroline Quéant, Pierre Blanchet, Véronic Landry, Diane Schorr

Bibliographic record

VenueJournal of Polymer Engineering · 2018
Typearticle
Languageen
FieldEngineering
TopicWood Treatment and Properties
Canadian institutionsUniversité Laval
Fundersnot available
KeywordsCoatingMaterials sciencePhotodegradationPolymerRaman spectroscopyChemical engineeringMethacrylateAcrylateUltravioletComposite materialCopolymerCatalysisChemistryOrganic chemistryPhotocatalysisOptoelectronics

Abstract

fetched live from OpenAlex

Abstract One of the major issues in the wood industry is the durability of clear coatings. The addition of organic ultraviolet absorbers (UVAs) improves coating resistance by the absorption and conversion of UV radiation into harmless heat. Organic UVAs are, however, easily degraded by free radicals produced by photodegradation inside the polymer matrix and are prone to migration in the coating. In this study, commercial UVAs and hindered amine light stabilizers (HALS) entrapped into poly(methyl methacrylate) (PMMA) microspheres and CaCO3 templates coated with UV-responsive polymers were added into clear acrylic water-based coating formulation. Artificial accelerated weathering experiments were performed on each formulation. Raman spectroscopy mapping was performed to visualize the concentration and distribution of UVAs and HALS. This study also presents a comparison of the mechanical properties of coatings obtained by dynamic mechanical analysis. Results showed that coating mechanical properties were improved when using encapsulated UVAs and HALS inside PMMA microspheres. The color change of the wood and coating system was minimized and the production of photo-oxidation compounds in the binder was also limited.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.028
GPT teacher head0.249
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations16
Published2018
Admission routes1
Has abstractyes

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Same venueJournal of Polymer EngineeringSame topicWood Treatment and PropertiesFrench-language works237,207