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Record W2913650376 · doi:10.1002/cjce.23464

Laboratory measurements of solubility and swelling factor for CO<sub>2</sub>/Brine and CO<sub>2</sub>/heavy oil binary systems under low‐medium pressure and temperature

2019· article· en· W2913650376 on OpenAlexaffvenue
Tayebeh Jamshidi, Fanhua Zeng, Paitoon Tontiwachwuthikul, Farshid Torabi

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2019
Typearticle
Languageen
FieldEngineering
TopicPhase Equilibria and Thermodynamics
Canadian institutionsUniversity of Regina
Fundersnot available
KeywordsSolubilityBrineDissolutionChemistryAnalytical Chemistry (journal)ChromatographyOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract An extensive experimental study was performed to investigate the effect of various parameters such as temperature, pressure, and crude oil API gravity on the fluid interactions in the binary systems of brine‐CO 2 and two heavy oil‐CO 2 systems. The solubility of CO 2 in 20 000 ppm brine solution was measured at various experimental conditions. The solubility of CO 2 and swelling factor, due to the CO 2 dissolution, of two heavy crude oil samples (type‐I: °API = 20.44 and type‐II: °API = 15.49) were experimentally measured at various operating conditions. Results showed that the solubility of CO 2 in heavy oil increased when the experimental pressure increased, and when the experimental temperature decreased. At a constant pressure of P exp = 3.44 MPa, the solubility of the CO 2 was measured to be 10.13, 5.72 g CO 2 /100 g oil in the type‐I crude oil when the temperature increased from T = 21 to 45 °C. Increasing the experimental pressure from P exp = 1.38 MPa to 3.44 MPa at a constant temperature of T = 21 °C increased the solubility of the CO 2 from 2.37 to 7.84 g CO 2 /100 g oil in the type‐II crude oil. The reduction in the oil API gravity had an adverse effect on the CO 2 solubility. At a temperature of T = 21 °C and a pressure of P exp = 3.44 MPa, the CO 2 solubility decreased from ∼10.13 in the type‐I oil to 7.84 g CO 2 /100 g oil in the type‐II oil. The measured values of the swelling factor showed that the type‐I and type‐II crude oils could exhibit a maximum swelling factor of 1.079 and 1.052 at a temperature of T = 21 °C and a pressure of P exp = 3.44 MPa.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.037
Threshold uncertainty score0.929

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.192
Teacher spread0.183 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2019
Admission routes2
Has abstractyes

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