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Record W2914040497 · doi:10.1373/clinchem.2018.289694

Mass Spectrometry-Based Tissue Imaging: The Next Frontier in Clinical Diagnostics?

2019· article· en· W2914040497 on OpenAlexaff
Felix Leung, Lívia S. Eberlin, Kristina Schwamborn, Ron M. A. Heeren, Nicholas Winograd, R. Graham Cooks

Bibliographic record

VenueClinical Chemistry · 2019
Typearticle
Languageen
FieldChemistry
TopicMass Spectrometry Techniques and Applications
Canadian institutionsMount Sinai Hospital
Funders's Heeren Loo
KeywordsContext (archaeology)Mass spectrometry imagingMALDI imagingPathologyGold standard (test)Tissue sampleComputational biologyBiological tissueBiomoleculeComputer scienceBiomedical engineeringMedicineMass spectrometryChemistryBiologyRadiologyNanotechnologyMaterials scienceChromatographyMatrix-assisted laser desorption/ionization

Abstract

fetched live from OpenAlex

The diagnosis of tissue samples traditionally has been performed by anatomic pathologists using a combination of cellular staining and light microscopy. With these techniques, pathologists can characterize various tissue features including cell morphology, structure, and composition to subsequently confirm whether a disease process is present. Although the histopathologic “gold-standard” methods are invaluable for routine tissue diagnosis, the results can be subjective, owing to a combination of factors such as variability in staining quality, nature of the sample, and human interpretation, and inconclusive for diseases that present indistinguishable histologic features. There is a need for new technologies that can be used as complementary tools in pathology for objective tissue analysis and disease diagnosis. Mass spectrometry (MS)7 imaging has been heralded as an upcoming advance in tissue analysis. The ability of MS to rapidly identify a variety of biomolecules present in a sample is highly attractive to the clinical laboratory. Indeed, MS coupled to chromatographic separation techniques is currently used to detect and/or quantify small molecules such as pharmacological agents and hormones in blood and urine. The advent of MS techniques that allow direct tissue analysis, including MALDI-MS and secondary ion MS, has allowed laboratories to extend the use of MS beyond biofluids into tissue samples. Using MALDI MS, for example, thin tissue sections can be analyzed in a nontargeted manner for the abundance and spatial distribution of biomolecules. As such, MALDI-MS imaging is being increasingly applied in clinical research, especially in the context of cancer diagnostics based on tissue proteomic and lipidomic signatures. The potential of MS in revolutionizing tissue analysis and diagnosis has driven several advances to accelerate its feasibility and utility in the clinical setting. The development of ambient ionization MS (AIMS), for example, has brought MS-based tissue imaging even closer to routine clinical use. Unlike MALDI and …

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.905
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.002
Insufficient payload (model declined to judge)0.0190.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.032
GPT teacher head0.353
Teacher spread0.321 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations23
Published2019
Admission routes1
Has abstractyes

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